We report the attempt of optical quantization and coding in 5-bit parallel format for photonic A/D conversion. The proposed system is designed to realize generation of 32 different optical codes in proportion to the corresponding signal levels when fed a certain range of amplitude-varied input pulses to the setup. Optical coding in a bit-parallel format made it possible, that provides 5bit optical codes from 32 optical quantized pulses. The 5-bit parallel operation of an optical quantization and coding module with 5 multi-ports was tested in our experimental setup.